In order to convert sunlight into electricity or other forms of energy as efficiently as possible, the very first step is an efficient light-harvesting system. Ideally, this should be panchromatic, i.e. absorb the entire spectrum of visible light.
The light-collecting antennae of plants and bacteria are a model for this. They capture a broad spectrum of light for photosynthesis, but are very complex in structure and require many different dyes to transmit the energy of the absorbed light and focus it on a central point.
Researchers at Julius-Maximilians-Universität (JMU) Würzburg in Bavaria, Germany, in the journal Chem have now presented an innovative light-harvesting system that differs significantly from previous systems.
"Our system has a band structure similar to that of inorganic semiconductors. This means that it absorbs light panchromatically across the entire visible range. And it uses the high absorption coefficients of organic dyes. As a result, it can absorb a great deal of light energy in a relatively thin layer, similar to natural light-harvesting systems," says JMU chemistry professor Frank Würthner. His team from the Institute of Organic Chemistry / Center for Nanosystems Chemistry designed the light-harvesting system at JMU and investigated it together with Professor Tobias Brixner's group from the Institute of Physical and Theoretical Chemistry.
Put simply, the innovative light-harvesting antenna from Würzburg consists of four different merocyanine dyes that are folded and thereby stacked closely together. The elaborate arrangement of the molecules enables ultra-fast and efficient energy transport within the antenna.
Source: https://www.sciencedaily.com/
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Materials provided by University of Würzburg. Original written by Robert Emmerich. Note: Content may be edited for style and length.
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